TY  - BOOK
AU  - Carraher,Charles E.
TI  - Introduction to polymer chemistry
SN  - 9781498737616 
AV  - QD381 .C37 2017
PY  - 2017///]
CY  - Boca Raton, FL
PB  - CRC Press, Taylor & Francis Group
KW  - Polymers
KW  - Polymerization
N1  - Includes bibliographical references and index; Chapter 1; Introduction to Polymers; 1.1; History of Polymers --; 1.2; Why Polymers? --; 1.3; Today's Marketplace --; 1.4; Environmental Assessment --; 1.4.1; Environmental Impact Assessment --; 1.4.2; Ecological Footprint --; 1.4.3; Life Cycle Assessment --; 1.5; Managing Sustainability --; Chapter 2; Polymer Structure (Morphology); 2.1; Stereochemistry of Polymers --; 2.2; Molecular Interactions --; 2.2.1; Glass Transition and Melt Transition --; 2.2.2; Secondary Structures --; 2.3; Polymer Crystals --; 2.4; Amorphous Bulk State --; 2.5; Polymer Structure-Property Relationships --; 2.6; Crystalline and Amorphous Combinations --; 2.7; Cross-Linking --; Chapter 3; Molecular Weight of Polymers; 3.1; Introduction --; 3.2; Solubility --; 3.2.1; Basic Concepts --; 3.2.2; Theoretical Approaches to Solubility --; 3.3; Average Molecular Weight Values --; 3.4; Fractionation of Polydisperse Systems --; 3.5; Chromatography --; 3.5.1; General Chromatography --; 3.5.2; lon-Exchange Chromatography --; 3.5.3; Affinity Chromatography --; 3.5.4; High-Performance Liquid Chromatography --; 3.5.5; Electrophoresis --; 3.5.6; Gel Permeation Chromatography --; 3.5.7; Size Exclusion Chromatography --; 3.6; Colligative Molecular Weights --; 3.6.1; Osmometry --; 3.6.2; End-Group Analysis --; 3.6.3; Ebulliometry and Cryometry --; 3.7; Light-Scattering Photometry --; 3.8; Other Techniques --; 3.8.1; Ultracentrifugation --; 3.8.2; Mass Spectrometry --; 3.9; Viscometry --; 3.9.1; Solution Viscosity --; 3.9.2; Melted Polymer Viscosities --; Chapter 4; Naturally Occurring Polymers; 4.1; Polysaccharides --; 4.2; Cellulose --; 4.2.1; Paper --; 4.2.2; Paper Recycling --; 4.3; Cellulose-Regenerating Processes --; 4.3.1; Dissolving and Precipitation of Cellulose --; 4.3.2; Wrinkle-Free Fabric --; 4.4; Esters and Ethers of Cellulose --; 4.4.1; Inorganic Esters --; 4.4.2; Organic Esters --; 4.4.3; Organic Ethers --; 4.5; Starch --; 4.6; Other Polysaccharides --; 4.6.1; Glycogen --; 4.6.2; Dextrans --; 4.6.3; Chitin --; 4.6.4; Chitosan --; 4.6.5; Heparin --; 4.6.6; Hyaluronic Acid --; 4.6.7; Chondroitin Sulfates --; 4.6.8; Arabinogalactans --; 4.6.9; Carrageenans, Agar, and Agarose --; 4.7; Proteins --; 4.7.1; Basics --; 4.7.2; Primary Structure --; 4.7.3; Secondary Structure --; 4.7.3.1; Keratins --; 4.7.3.2; Silk --; 4.7.3.3; Wool --; 4.7.4; Tertiary Structure --; 4.7.4.1; Globular Proteins --; 4.7.4.2; Fibrous Proteins --; 4.7.4.3; Elastin --; 4.7.4.4; Membrane Proteins --; 4.7.5; Quaternary Structure --; 4.8; Nucleic Acids --; 4.8.1; Basics --; 4.8.2; Flow of Biological Information --; 4.8.3; Next Steps --; 4.9; Naturally Occurring Polyisoprenes and Other Synthetic Elastomers --; 4.9.1; Balloons --; 4.9.2; Resins --; 4.9.3; Rosin and Related Materials --; 4.10; Lignin --; 4.11; Melanins --; 4.12; Polymer Structure --; 4.13; Genetic Engineering --; 4.14; DNA Profiling --; 4.15; Asphalt --; Chapter 5; Step-Reaction Polymerization (Polycondensation Reactions); 5.1; Comparison between Polymer Type and Kinetics of Polymerization --; 5.2; Introduction --; 5.3; Stepwise Kinetics --; 5.4; Polycondensation Mechanisms --; 5.5; Polyesters and Polycarbonates --; 5.6; Synthetic Polyamides --; 5.7; Polymides --; 5.8; Polybenzimidazoles and Related Polymers --; 5.9; Polyurethanes and Polyureas --; 5.10; Polysulfides --; 5.11; Polyethers --; 5.12; Polysulfones --; 5.13; Poly(Ether Ether Ketone) and Polyketones --; 5.14; Phenolic and Amino Plastics --; 5.15; Synthetic Routes --; 5.16; Liquid Crystals --; 5.17; Microfibers --; Chapter 6; Ionic Chain Reaction and Complex Coordination Polymerization (Addition Polymerization); 6.1; Cationic Polymerization --; 6.1.1; Kinetics of Cationic Polymerization --; 6.1.2; Poly(Vinyl Isobutyl Ether) --; 6.1.3; Polyoxymethylene --; 6.1.4; Poly(Ethylene Oxide) --; 6.1.5; Polyterpenes and Related Polymers --; 6.2; Anionic Polymerization --; 6.2.1; Kinetics of Anionic Polymerization --; 6.2.2; Cis-1,4-Polyisoprene --; 6.2.3; Living Polymers --; 6.3; Stereoregularity and Stereogeometry --; 6.4; Polymerization with Complex Coordination Catalysts --; 6.5; Soluble Stereoregulating Catalysis --; 6.6; Polyethylenes --; 6.6.1; Introduction Polyethylenes --; 6.6.2; High-Density Polyethylene --; 6.6.3; Linear Low-Density Polyethylene --; 6.6.4; Very-Low-Density Polyethylene --; 6.6.5; Ultrahigh-Molecular-Weight Polyethylene --; 6.6.6; Ultralinear Polyethylene --; 6.6.7; Cross-Linked Polyethylene --; 6.6.8; Medium-Density Polyethylene --; 6.6.9; Polymethylene --; 6.6.10; Shopping Bags --; 6.7; Polypropylene --; 6.7.1; History --; 6.7.2; Stereospecific Structures --; 6.7.3; Early Production --; 6.7.4; Forms of Polypropylene --; 6.8; Polymers from 1,4-Dienes --; 6.8.1; Introduction --; 6.8.2; Butadiene Rubber --; 6.8.3; ABS --; 6.8.4; High-Impact Polystyrene --; 6.8.5; Polyisoprene --; 6.8.6; Polychloroprene --; 6.9; Polyisobutylene --; 6.10; Metathesis Reactions --; 6.11; Zwitterionic Polymerization --; 6.12; Isomerization Polymerization --; 6.13; Precipitation Polymerization --; Chapter 7; Free Radical Chain Polymerization (Addition Polymerization); 7.1; Initiators for Free Radical Chain Polymerization --; 7.2; Mechanism for Free Radical Chain Polymerization --; 7.3; Chain Transfer --; 7.4; Polymerization Techniques --; 7.4.1; Bulk Polymerization --; 7.4.2; Suspension Polymerization --; 7.4.3; Solution Polymerization --; 7.4.4; Emulsion Polymerization --; 7.5; Fluorine-Containing Polymers --; 7.5.1; Polytetrafluoroethylene --; 7.5.2; Poly(Vinyl Fluoride) --; 7.5.3; Other Fluorine-Containing Polymers --; 7.6; Polystyrene --; 7.7; Poly(Vinyl Chloride) --; 7.8; Poly(Methyl Methacrylate) --; 7.9; Polyacrylonitrile --; 7.10; Solid-State Irradiation Polymerization --; 7.11; Plasma Polymerizations --; Chapter 8; Copolymerization; 8.1; Kinetics of Copolymerization --; 8.2; The Q-e Scheme --; 8.3; Commercial Copolymers --; 8.4; Block Copolymers --; 8.5; Graft Copolymers --; 8.6; Elastomers --; 8.6.1; General --; 8.6.2; Thermoplastic Elastomers --; 8.6.3; SBR Copolymers --; 8.6.4; Sales and Flammability --; 8.7; Blends --; 8.7.1; General --; 8.7.2; Immiscible Blends --; 8.7.3; Immiscible Blends: Remainder of the Section on Immiscible Blends --; 8.7.4; Miscible Blends --; 8.8; Polymer Mixtures: IPNs and Alloys --; 8.9; Dendrites --; 8.10; lonomers --; 8.11; Fluoroelastomers --; 8.12; Nitrile Rubber --; 8.12.1; Laboratory Gloves --; 8.13; Acrylonitrile Butadiene Styrene Terpolymers --; 8.14; EPDM Rubber --; Chapter 9; Organometallic and Metalloid Polymers; 9.1; Introduction --; 9.2; Inorganic Reaction Mechanisms --; 9.3; Condensation Organometallic Polymers --; 9.4; Coordination Polymers --; 9.5; Addition Polymers --; Chapter 10; Inorganic Polymers; 10.1; Introduction --; 10.2; Portland Cement --; 10.3; Other Cements --; 10.4; Silicates --; 10.4.1; Network --; 10.4.2; Layer --; 10.4.3; Chain --; 10.5; Silicon Dioxide (Amorphous) --; 10.5.1; Kinds of Glass --; 10.5.2; Safety Glass --; 10.5.3; New Applications of Glass --; 10.5.4; Seeing Glass Lenses --; 10.6; Sol-Gel --; 10.6.1; Aerogels --; 10.7; Silicon Dioxide (Crystalline Forms): Quartz Forms --; 10.8; Silicon Dioxide in Electronic Chips --; 10.9; Asbestos --; 10.10; Fly Ash and Aluminosilicates --; 10.11; Polymeric Carbon: Diamond --; 10.12; Polymeric Carbon: Graphite --; 10.13; Internal Cyclization: Carbon Fibers and Related Materials --; 10.14; Carbon Nanotubes --; 10.14.1; General --; 10.14.2; Structures --; 10.14.3; Properties --; 10.14.3.1; Electrical --; 10.14.3.2; Mechanical --; 10.14.3.3; Field Emission --; 10.14.3.4; Hydrogen and Ion Storage --; 10.14.3.5; Chemical and Genetic Probes --; 10.14.3.6; Analytical Tools --; 10.14.3.7; Superconductors --; 10.14.4; Health Issues --; 10.14.5; Potential --; 10.15; Bitumens --; 10.16; Carbon Black --; 10.17; Polysulfur --; 10.18; Ceramics --; 10.19; High Temperature Superconductors --; 10.19.1; Discovery of the 123-Compound --; 10.19.2; Structure of the 123-Compound --; 10.20; Zeolites --; Chapter 11; Reactions of Polymers; 11.1; Reactions with Polyolefins and Polyenes --; 11.2; Reactions of Aromatic and Aliphatic Pendant Groups --; 11.3; Degradation --; 11.4; Cross-Linking --; 11.5; Reactivities of End; Groups --; 11.6; Supramolecules and Self-Assembly --; 11.7; Transfer and Retention of Oxygen --; 11.8; Nature's Macromolecular Catalysts --; 11.9; Photosynthesis --; 11.9.1; General --; 11.9.2; Purple Photosynthetic Bacteria --; 11.9.3; Green Sulfur Bacteria --; 11.10; Mechanisms of Physical Energy Absorption --; 11.11; Breakage of Polymeric Materials --; Chapter 12; Testing and Spectrometric Characterization of Polymers; 12.1; Spectronic Characterization of Polymers --; 12.1.1; Infrared Spectroscopy --; 12.1.2; Raman Spectroscopy --; 12.1.3; Nuclear Magnetic Resonance Spectroscopy --; 12.1.4; NMR Applications --; 12.1.5; Electron Paramagnetic Resonance Spectroscopy --; 12.1.6; X-Ray Spectroscopy --; 12.2; Surface Characterization --; 12.2.1; Attenuated Total Reflectance --; 12.2.2; Auger Electron Spectroscopy and X-Ray Photoelectron Spectroscopy --; 12.2.3; Near-Field Scanning Optical Microscopy --; 12.2.4; Electron Microscopy --; 12.2.5; Scanning Probe Microscopy --; 12.2.6; Secondary Ion Mass Spectroscopy --; 12.2.7; Superresolution Fluorescence Microscopy --; 12.3; Amorphous Region Determinations --; 12.4; Thermal Analysis --; 12.5; Thermal Property Tests --; 12.5.1; Thermal Conductivity --; 12.5.2; Thermal Expansion --; 12.5.3; Glass Transition Temperatures --; 12.6; Flammability --; 12.7; Electrical Properties: Theory --; 12.8; Electric Measurements --; 12.9; Weatherability --; 12.10; Optical Property Tests --; 12.10.1; Index of Refraction --; 12.10.2; Optical Clarity --; 12.10.3; Absorption and Reflectance --; 12.11; Chemical Resistance --; Chapter 13; Rheology and Physical Tests; 13.1; Rheology --; 13.1.1; Rheology and Physical Tests --; 13.1.2; Response Time --; 13.2; Typical Stress-Strain Behavior --; 13.3; Stress-Strain Relationships --; 13.4; Specific Physical Tests --; 13.4.1; Tensile Strength --; 13.4.2; Tensile Strength of Inorganic and Metallic Fibers and Whiskers --; 13.4.3; Hardness --; 13.4.4; Failure --; Chapter 14; Additives; 14.1; Fillers --; 14.2; Reinforcements --; 14.2.1; Fibers and Resins --; 14.2.2; Applications --; 14.3; Nanocomposites --; 14.4; Plasticizers --; 14.5; Antioxidants --; 14.6; Heat Stabilizers --; 14.7; Ultraviolet Stabilizers --; 14.8; Flame Retardants --; 14.9; Colorants --; 14.10; Curing Agents --; 14.11; Antistatic Agents: Antistats --; 14.12; Chemical Blowing Agents --; 14.13; Compatibilizers --; 14.14; Impact Modifiers --; 14.15; Processing Aids --; 14.16; Lubricants --; 14.17; Microorganism Inhibitors --; Chapter 15; Synthesis of Reactants and Intermediates for Polymers; 15.1; Monomer Synthesis from Basic Feedstocks --; 15.2; Reactants for Step-Reaction Polymerization --; 15.3; Synthesis of Vinyl Monomers --; 15.4; Search for Less Expensive Feedstocks --; Chapter 16; Polymer Technology; 16.1; Polymer Processing --; 16.1.1; General --; 16.1.2; Secondary Structures: Mesophases --; 16.2; Fibers --; 16.2.1; Polymer Processing: Spinning and Fiber Production --; 16.2.1.1; Introduction --; 16.2.1.2; Melt Spinning --; 16.2.1.3; Dry Spinning --; 16.2.1.4; Wet Spinning --; 16.3; Elastomers --; 16.3.1; Elastomer Processing --; 16.4; Films and Sheets --; 16.4.1; Calendering --; 16.5; Polymeric Foams --; 16.6; Reinforced Plastics (Composites) and Laminates --; 16.6.1; Composites --; 16.6.2; Particle-Reinforced Composites: Large-Particle Composites --; 16.6.3; Fiber-Reinforced Composites --; 16.6.4; Processing of Fiber-Reinforced Composites --; 16.6.5; Structural Composites --; 16.6.6; Laminating --; 16.7; Molding --; 16.7.1; Injection Molding --; 16.7.2; Blow Molding --; 16.7.3; Rotational Molding --; 16.7.4; Compression and Transfer Molding --; 16.7.5; Thermoforming --; 16.8; Casting --; 16.9; Extrusion --; 16.9.1; Processing --; 16.9.2; Rainwear --; 16.10; Coatings --; 16.11; Adhesives --; 16.12; Conductive Polymeric Materials --; 16.12.1; Photoconductive and Photonic Polymers --; 16.12.2; Electrically Conductive Polymers --; 16.13; Drug Design and Activity --; 16.14; Synthetic Biomedical Polymers --; 16.15; Dental Materials --; 16.16; Emerging Polymers --; 16.17; Green Materials
N2  - "Introduction to Polymer Chemistry provides undergraduate students with a much-needed, well-rounded presentation of the principles and applications of natural, synthetic, inorganic, and organic polymers. With an emphasis on the environment and green chemistry and materials, this fourth edition continues to provide detailed coverage of natural and synthetic giant molecules, inorganic and organic polymers, elastomers, adhesives, coatings, fibers, plastics, blends, caulks, composites, and ceramics. Building on undergraduate work in foundational courses, the text fulfills the American Chemical Society Committee on Professional Training (ACS CPT) in-depth course requirement."--Publisher's description
ER  -